Selection guide - ten decisions alloy wire buyers keep re-making.

Each note answers one question in operating terms: in what conditions do you choose A over B. All values are nominal and are confirmed on the batch inspection report.

How to choose a thermocouple type: K vs E vs J vs T

The four types differ in range, sensitivity and the atmosphere they tolerate. Pick the type by whichever constraint is binding for your process - not by habit.

TypePositive legNegative legRangeSensitivityBest-fit duty
KNiCrNiSi-200 … +1350 °CMediumGeneral industrial, widest range
ENiCuConstantan-200 … +900 °CHighestLow-to-mid temperature where sensitivity is critical
JIronConstantan-210 … +760 °CLow-mediumReducing atmospheres, low-to-mid temperature
TCopperConstantan-250 … +350 °CMediumLowest temperature, highest precision of the four

Decision rule - pick the type by the binding constraint

  1. Range is the constraint -> K. It is the only one of the four rated to about 1350 °C.
  2. Sensitivity at low-to-mid temperature is the constraint -> E. Highest EMF output, so the smallest signal error when the instrument is limited.
  3. A reducing or acid-fume atmosphere is the constraint -> J. The iron leg is the only one that tolerates it.
  4. Lowest temperature and highest accuracy is the constraint -> T. The copper leg is the most precise at the bottom of the range.

Common cross-choices

  • K vs E around 800 °C: K for durability and range; E when the instrument needs maximum signal and the range can stop at 900 °C.
  • K vs J: J wins only in a reducing atmosphere; otherwise K is broader.
  • E vs T below 350 °C: T for the lowest, most stable reading; E when you need sensitivity up to 900 °C.
  • K vs T above 350 °C: K - the copper leg of T cannot reach the upper range.

Constantan vs manganin - when to pick one over the other

PropertyConstantan 6J40 (Cu-Ni)Manganin 6J8 / 6J12 / 6J13 (Cu-Mn-Ni)
CompositionCu approx. 55 %, Ni approx. 45 %Cu base with Mn and Ni
Resistivity @ 20 °CHigh, similar magnitude - per batch reportHigh, similar magnitude - per batch report
TCR @ 20 °CNear zeroVery low (slightly lower than constantan)
Thermal EMF vs copperLowVery low; 6J13 the lowest
Standard roleE / J / T thermocouple negative leg; wire-wound and sampling resistorsStandard resistors, precision shunts, ratio bridges, metering

Decision rule

  • A thermocouple negative leg (type E, J or T) -> constantan. It is the specified negative-leg metal. Do not substitute manganin or the reference table no longer matches.
  • A standard resistor, precision shunt, metering element or ratio bridge, with the lowest TCR and thermal EMF required -> manganin, and 6J13 where thermal EMF against copper must be as small as possible.
  • A wire-wound or sampling resistor -> constantan, or a Cu-Ni NC grade when the target resistivity sits far from the 0.5 µΩ·m region.
  • Cost matters and the duty is a general power or sampling resistor -> constantan; keep manganin for precision metrology.

The one rule that ends most debates: constantan is chosen by application, manganin is chosen by a precision requirement. No precision metering requirement? Default to constantan.

Cu-Ni (NC) vs constantan - low resistance vs low temperature coefficient

Both are copper-nickel alloys, but they solve different problems: one hits a resistance value, the other holds it steady.

PropertyCu-Ni NC003 - NC050Constantan 6J40 (Cu55Ni45)
Composition familyGraded Cu-Ni seriesFixed approx. 55 Cu / 45 Ni
Resistivity @ 20 °Capprox. 0.03 - 0.50 µΩ·m (graded, per GB/T 6454-2008)Confirmed on the batch inspection report
Primary traitLow, controllable resistance valueLow temperature coefficient (TCR)
RoleShunt / sampling / power / braking resistor, load bankThermocouple leg, sampling and wire-wound resistor, metering

Decision rule

  • A specific low resistance value, with normal TCR acceptable -> NC series. Pick the grade whose resistivity hits your target; more nickel means higher resistivity.
  • Resistance that must stay constant across a temperature swing -> constantan. Its TCR is near zero, so the value barely moves.
  • A thermocouple negative leg -> constantan. NC grades are not used as thermocouple legs.

In one line: NC means "I need a target resistance value". Constantan means "I need a temperature-stable resistance".

Pure nickel N4 vs N6 - which purity grade for your application

PropertyN4 · Ni201N6 · Ni200
Nickel content≥ 99.0 %≥ 99.5 %
Resistivity @ 20 °CLow - per batch inspection reportLow - per batch inspection report (the lowest of the two)
Oxidation resistanceGoodExcellent
Sealing and joint integrityGoodBest, to glass and ceramic
Relative costLowerHigher (higher purity)

Decision rule

  • Conductivity, low-loss leads, or sealing to glass or ceramic is the priority -> N6. The extra purity lowers resistivity and gives the most reliable seal.
  • General nickel duty at lower cost (mesh, woven cloth, ordinary corrosion parts, ordinary leads) -> N4.
  • A thermocouple leg is needed -> use the thermocouple family. Pure nickel is a lead material, not a thermocouple metal.

Monel 400 vs copper-nickel (NC) - corrosion-first vs value-first

PropertyMonel 400Cu-Ni NC series
Compositionapprox. 70 % Ni - 30 % CuGraded, Cu-rich through Ni-rich
Resistivity @ 20 °CHigh - per batch inspection reportapprox. 0.03 - 0.50 µΩ·m (graded)
Primary traitCorrosion resistance in aggressive serviceLow, controllable resistance value
RoleStructural and fastening wire, marine and nuclear, specialty weldingShunts, sampling and power resistors, load banks

Decision rule

  • Corrosion resistance is the binding constraint (seawater, hydrofluoric acid, alkalis, chemical or nuclear-adjacent service) -> Monel 400. NACE MR0175 by arrangement for sour service.
  • A specific low resistance value or a resistor function is needed -> NC series. Monel's resistivity is too high for most low-resistance shunt work.
  • Strength at moderate temperature in a corrosive environment, with no resistance function -> Monel. A copper-rich NC grade would corrode faster.

In one line: pick Monel when the environment is the specification; pick an NC grade when the electrical value is the specification.

NiCr 80/20 vs NiCr 60/15 - the type K positive leg

These are composition variants of the type K positive-leg alloy, not two different thermocouple types. The numbers refer to the nominal nickel and chromium portions of the positive metal; the balance is the fixed silicon and manganese content that gives type K its EMF behaviour.

VariantNominal positive-leg make-upTypical use
NiCr 80/20Approx. 80 % Ni / 20 % CrStandard type K; widest availability; the conventional instrument and probe wire
NiCr 60/15Lower nickel, higher-alloy positive-leg variantDuty where the alloy must be shifted - a higher-chromium window for hot corrosion, or a specific range and EMF trade-off

Decision rule

  • Standard industrial type K, and the published reference tables (IEC 60584-1 / ASTM E230) must match -> NiCr 80/20. The published EMF tables assume the conventional positive leg.
  • A positive leg tuned for a specific high-temperature or hot-corrosion window -> NiCr 60/15.
  • The reading must be correct against the published type K tables -> stay on 80/20. A variant leg changes the EMF curve and must be calibrated, not treated as a drop-in.

In one line: default to NiCr 80/20 for standard type K; move to 60/15 only when the operating window demands the alloy shift, and re-pair the negative leg and re-verify against the reference table, because a composition change is not a calibration-neutral swap.

Choosing the temper: soft (M) vs half-hard (Y2) vs hard (Y)

TemperDuctilityTensile and springBest for
M (soft / annealed)MaximumLowestWinding, braiding, mesh, most resistance elements
Y2 (half-hard)ModerateModerateParts that need some stiffness but must still bend or wind
Y (hard / as-drawn)LowHighestStructural wire, electrodes, parts that must hold their own shape

Decision rule

  • You will wind it (mesh, cloth, resistor, coil) -> M. Maximum ductility means the most passes without fracture.
  • It must keep a formed shape but still be worked a little -> Y2.
  • It is structural, an electrode or a spring -> Y. Highest tensile; use where the wire must not creep.

Practical notes

  • Finer diameters fracture more easily in hard temper, so at the ultra-fine end (0.018 mm) most duty stays in M or Y2.
  • A single order can mix tempers per spool if the application varies - state the split on the drawing.
  • Temper affects spring-back in forming and therefore final part dimensions; call this out with the tolerance when a fitted part is involved.

Shunt resistor material: Cu-Ni (NC), constantan or manganin

MaterialResistivity @ 20 °CTCRWhen it wins
Cu-Ni NC grade0.03 - 0.50 µΩ·m (graded)NormalA specific low resistance value; power, braking and load-bank duty
Constantan 6J40Per batch inspection reportNear zeroA temperature-stable shunt in a metering range; general sampling resistor
Manganin 6J12 / 6J13Per batch inspection reportVery lowStandard resistors, precision shunts, lowest thermal EMF against copper

Decision rule

  • The shunt must hit a target resistance value and carry power -> a Cu-Ni NC grade. More nickel means higher resistivity.
  • The shunt is in a metering range and its value must stay constant as temperature swings -> constantan 6J40. Near-zero TCR means the reading does not drift with self-heating.
  • A standard or precision shunt, or a metering bridge, where thermal EMF against the copper connecting wire must be minimised -> manganin, and 6J13 for the lowest thermal EMF.

In one line: value-driven (power, load bank) -> Cu-Ni NC. Temperature-stability-driven (metering range) -> constantan. Precision or lowest thermal EMF (ratio bridge) -> manganin 6J13. Confirm TCR against the self-heating limit before locking the grade.

Choosing wire for a mineral-insulated (MI) thermocouple cable

An MI cable pulls bare thermocouple legs through a sheathed conductor. The wire has to meet three requirements at once: a thermocouple type matched to the duty temperature, a fine enough diameter for the sheath, and consistent thermal EMF along the whole cable.

Decision rule

  • The duty temperature range. General industrial up to about 1350 °C -> type K, the default MI cable core. High sensitivity at low-to-mid temperature -> type E. Reducing atmosphere or acid fumes -> type J. Lowest temperature and highest precision -> type T.
  • The conductor diameter. Small-diameter sheaths need the fine end of the 0.10 - 6.00 mm range; larger sheaths take a mid-to-large gauge. Confirm the gauge against the sheath inner diameter so the legs and filler compress cleanly.
  • The temper. MI conductors are drawn into the sheath, so soft temper (M) is the correct condition - maximum drawability, least fracture risk.

In one line: pick the type from the temperature range and atmosphere, use the soft temper, match the gauge to the sheath inner diameter, and order the legs as a matched pair so the thermal-EMF behaviour of the whole cable is consistent.

What to specify before you quote precision alloy wire - five fields

Most late-stage failures are not the wire. They are a specification that was never pinned down: a tolerance that silently widened, a document the receiving QA asks for that was never quoted, or a paired thermocouple shipped as two unmatched spools. Fix these five in writing before quotation.

  1. Grade or family. Which of the six families, and the exact grade - 6J40 constantan, N6 pure nickel, NC025, type K legs. If you only know the application (a shunt, a thermocouple, a heating lead), state that and we will propose grade and gauge.
  2. Diameter and tolerance. Nominal diameter within 0.018 - 6.00 mm, and the tolerance window. The tighter the window, the more draw passes and the lower the yield - a tighter window costs. State the window you actually need.
  3. Temper. M (soft) for winding and drawing, Y2 for stiffness-with-work, Y for structural duty that must hold shape.
  4. Quantity and entry point. A 100 g sample supplied at cost, minimum order 1 kg, production pricing from 5 kg. There is no container minimum; freight cost per kilogram is what scales, so consolidating the first order beats splitting it.
  5. Document requirement. Material test certificate (standard with every shipment), EN 10204 3.1 inspection certificate, third-party (CNAS) test report, thermal-EMF pairing data, RoHS and REACH declarations. Set the exact standard, edition and certificate type before the order - it affects lead time and price, not just paperwork.

In one line: send grade, diameter and tolerance, temper, quantity, and the exact document list - in writing. If you only know the application, send that and let us propose the grade and gauge, then confirm the spec in writing before anyone commits.

Last updated: 15 October 2026. Values on this page are nominal - resistivity, temperature coefficient of resistance, thermal EMF and mechanical properties are confirmed by the inspection report issued with each shipment. The international standards cited are given as the nearest reference for buyers comparing designations; formal certification to a named standard is confirmed in writing on the quotation.

Send the grade, diameter, temper and quantity.

Tell us what the wire has to do and the date your line needs it. We come back with a confirmed lead time, the achievable tolerance and the documents we can issue. Sample 100 g at cost; orders from 1 kg; production pricing from 5 kg.